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Quantum Thermodynamics

by Patrick P. Potts

Submission summary

Authors (as registered SciPost users): Patrick Potts
Submission information
Preprint Link: https://arxiv.org/abs/2406.19206v2  (pdf)
Date submitted: Dec. 18, 2025, 10:03 a.m.
Submitted by: Patrick Potts
Submitted to: SciPost Physics Lecture Notes
Ontological classification
Academic field: Physics
Specialties:
  • Quantum Physics
Approach: Theoretical

Abstract

The theory of quantum thermodynamics investigates how the concepts of heat, work, and temperature can be carried over to the quantum realm, where fluctuations and randomness are fundamentally unavoidable. These lecture notes provide an introduction to the thermodynamics of small quantum systems. It is illustrated how the laws of thermodynamics emerge from quantum theory and how open quantum systems can be modeled by Markovian master equations. Quantum systems that are designed to perform a certain task, such as cooling or generating entanglement are considered. Finally, the effect of fluctuations on the thermodynamic description is discussed.

Author comments upon resubmission

Dear Editor, Dear Referee,

Thank you for the time and effort spent on my manuscript. I am happy that the Referee recommends acceptance with minor revisions. In particular, the Referee requests four changes which are fully addressed in the updated manuscript. I believe that with these changes, the manuscript is ready for publication in SciPost Physics Lecture Notes.

Yours sincerely,
Patrick Potts

List of changes

All equation and reference numbers refer to the updated manuscript.

Requests by the Referee:

  1. It is recommended to provide a more detailed explanation of the derivation from Eq. (120) to (122), specifically addressing how the term Tr{H_tot(t)∂_t ρ_tot} vanishes. This explanation could include a discussion on the commutation relationship between the Hamiltonian and the density matrix and how equilibrium conditions within the grand canonical ensemble, as referenced in Eq. (72), imply that the time derivative of the density matrix vanishes. Incorporating this detailed explanation will help students understand the underlying physical principles and mathematical steps more effectively, improving their grasp of quantum thermodynamics.

Response: I added the new Eq. (121) that clarifies why the corresponding term vanishes. However, this is a direct consequence of the unitary dynamics and is not related to any equilibrium conditions. No assumptions on the initial state are required for this.

  1. It is recommended that the explanation between Eq. (136) and Eq. (137) be expanded. The manuscript could greatly benefit from including intermediate steps or underlying assumptions that lead to this solution.

Response: I added text below Eq. (138), stating how it can be verified that Eq. (137) is indeed a solution to the second equation in Eq. (136). No assumptions need to be made. This solution can be obtained using standard methods for solving differential equations, like variation of constants. I did not provide an explicit derivation since I think it might be distracting and since there is an abundance of pedagogical resources covering differential equations.

  1. It is recommended to explicitly state the assumption that the system and the bath are uncorrelated before introducing Eq.(139).

Response: In the updated manuscript, this assumption is explicitly stated.

  1. To further enhance the understanding and application of superoperator and projection operator techniques within the lecture notes, it is recommended to include the following references in the bibliography: i) Mukamel, S. (1995). "Principles of Nonlinear Optical Spectroscopy," Oxford University Press. • This book provides an extensive overview of nonlinear optical spectroscopy and discusses how projection operator techniques can be utilized to understand the dynamics of quantum systems. It is a resource for theoretical foundations and practical applications relevant to the course material. ii) Levitov, L., Lee, H., and Lesovik, G. B. (1996). "Electron Counting Statistics and Coherent States of Electric Current," Journal of Mathematical Physics. • This article explores superoperators and projection operator techniques in analyzing electron transport statistics and quantum noise. It offers a detailed examination suitable for advanced studies and research in quantum mechanics and mesoscopic physics.

Response: I included a reference to the book by S. Mukamel (Ref. [62] in the updated manuscript). I did not include a reference to "Electron Counting Statistics and Coherent States of Electric Current" since this paper, while being a seminal contribution, does not explore superoperators and projector operator techniques.

Small changes: I fixed a number of typos and made some minor modifications. In particular, I slightly changed the presentation around Eq. (313), to improve accessibility. I also added the sentence "Figure adapted from Ref. [98]" to Fig. 16, I added Refs. [75,76] and updated references to preprints that have been published since the appearance of the first version, and I updated the acknowledgments.

Current status:
In refereeing

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